Methane Conversion to Liquid Fuels and Chemicals
Primary Research Goals
Leaders: Matteo Cargnello Tom Jaramillo Xiaoling Zheng
- Methane to hydrogen and high value carbon products
- Novel catalyst design and synthesis
- Pathways to e-fuels (e.g., methanol, ammonia)
Faculty and Researchers





Students
• Dongjae Kong, graduate student in the Zheng group. Dongjae has investigated the conditions for exsolved metallic nanoparticles from metal oxides.
• Lauren Vallez, graduate student in the Zheng group. Lauren has tested the stability of H2O2 due to homogeneous and heterogeneous disproportionation reactions. Lauren graduated in January of 2023.
• Yue Jiang, postdoc in the Zheng group. Yue investigated the synthesis of high entropy alloys as catalysts for methane pyrolysis. He left the group in July of 2023 and started a faculty position in China.
• Henry Moise, 2nd year PhD student in Cargnello group, Chemical Engineering, investigate the oxypyrolysis process for hydrogen and CNTs production.
• Sihe Zhang, 5th year PhD student in Jaramillo group, Chemical Engineering.
Research Groups
Cargnello Group - Focuses on the preparation and use of uniform and tailored materials for heterogeneous catalysis and photocatalysis and the technological exploitation of nanoparticles and nanocrystals. Reactions of interest are related to sustainable energy generation and use, control of emissions of greenhouse gases, and better utilization of abundant building blocks (methane, biomass).
Criddle Group - Focuses on environmental biotechnology and microbial ecology for clean water, clean energy, and healthy ecosystems. The group works on large interdisciplinary field projects, studies of microbial ecology in bioreactors, and work on microbial transformations of persistent contaminants.
Majumdar Group - Researches the science and engineering of nanoscale materials and devices, especially in the areas of energy conversion, transport and storage as well as biomolecular analysis. Current research focuses on electrochemical and thermochemical redox reactions that are fundamental to a sustainable energy future, multidimensional nanoscale imaging and microscopy, and a new effort to re-engineer the electricity grid using data science, including deep learning techniques.
Jaramillo Research Group - Recent years have seen an unprecedented motivation for the emergence of new energy technologies. Global dependence on fossil fuels, however, will persist until alternate technologies can compete economically. We must develop means to produce energy (or energy carriers) from renewable sources and then convert them to work as efficiently and cleanly as possible. Catalysis is energy conversion, and the Jaramillo laboratory focuses on fundamental catalytic processes occurring on solid-state surfaces in both the production and consumption of energy. Chemical-to-electrical and electrical-to-chemical energy conversion are at the core of the research.
Spormann Group - The research interests of the Spormann Group in our lab are at the interface of fundamental metabolic processes of anaerobic microorganisms and their application in bioenergy, bioremediation, and human intestinal health. We explore the distinguishing features of novel microbial metabolism and how molecular and biochemical differences in metabolism shape microbial fitness. We study novel microbial metabolism with relevance to bioremediation, bioenergy, and intestinal microbiology.
Xia Lab - The group is interested in the design, synthesis, and manipulation of novel organic and polymeric materials. They use a combination of organic and polymer chemistry, catalysis, and advanced characterizations to create, control, and investigate unusual (macro) molecular structures and organic materials with tailored conformations nanostructures, properties, and functions, which advance our fundamental understanding of emerging topics in chemistry and polymer science as well as target important technological applications.
Zheng Group - Studies the interfacial science among combustion, nanomaterials and energy conversion. Our goal is to bridge combustion science with scalable synthesis and applications of high-dimensional nanomaterials to provide innovative and revolutionary solutions to solve some of today’s most challenging problems, such as energy and the environment. The Zheng group is also interested in innovating new manufacture methods for flexible and attachable inorganic electronics.
Related Publications
- Averesch, N. J., Pane, V., Kracke, F., Ziesack, M., Nangle, S., Silver, P., & Waymouth, R. (2021). Biocatalytic Formation of Novel Polyesters with para-Hydroxyphenyl groups in the Backbone - Engineering Cupriavidus necator for production of high-performance materials from CO2 and electricity.
- Rutherford, J., Sherwin, E., Ravikumar, A., Heath, G., Englander, J., Cooley, D., Lyon, D., Omara, M., Langfitt, Q., & Brandt, A. (2021). Closing the methane gap in US oil and natural gas production emissions inventories. Nature Publishing Group, 12(1), 12-Jan.
- Schwalbe, J., Statt, M., Chosy, C., Rohr, B., & al, et . (2020). A Combined Theory-Experiment Analysis of the Surface Species in Lithium-Mediated NH3 Electrosynthesis. Chemistry Europe, 7(7), 1542-1549. https://doi.org/10.1002/celc.201902124
- K., R. M.-G. C. F. J. H. C. (2020). Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold.
- F., W. H. J. M.-G. C. H. J. (2020). Selective reduction of CO to acetaldehyde with CuAg electrocatalysts..
- S., C. A. G. W. B. H. G. C. C. B. (2019). Engineering of Ruthenium-Iron Oxide Colloidal Heterostructures Leads to Improved Yields in CO2 Hydrogenation to Hydrocarbons..
- M., G. J.-P. D. W. H. A.-P. B. P. C. (2019). Catalyst deactivation via decomposition into single atoms and the role of metal loading.
- M., G. J.-P. D. W. H. A.-P. B. P. C. (2019). Supported Catalyst Deactivation by Decomposition into Single Atoms Is Suppressed by Increasing Metal Loading.
- M., R. W. H. H. M. B. V. B. C. (2019). Transition state and product diffusion control by polymer-nanocrystal hybrid catalysts.
- Wang, J., Ji, J., Ravikumar, A., Savarese, S., & Brandt, A. (2019). VideoGasNet: Deep Learning for Natural Gas Methane Leak Classification Using an Infrared Camera. Pergamon, 121516.
- S., B. C. (2019). Can biotechnology turn the tide on plastics?.
- F., W. N. W. S. N. M.-G. O. H. H. J. (2019). Electrochemically converting carbon monoxide to liquid fuels by directing selectivity with electrode surface area.
- Chorkendorff I, N. B. S. L. E. H. S. S. C. H. N. J. (2019). Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte.
- H., D. L. H. H. J. J. S. (2019). What would it take for renewably powered electrosynthesis to displace petrochemical processes?.
- K., K. S. B. V. P. S. Z. N. (2019). ZnO As an Active and Selective Catalyst for Electrochemical Water Oxidation to Hydrogen Peroxide.
- T., C. R. T. W. H. J. C. B. (2019). Influence of Atomic Surface Structure on the Activity of Ag for the Electrochemical Reduction of CO2 to CO .
- F., S. S. H. C. V. U. S. D. G. A.-P. J. (2019). Revealing the Synergy between Oxide and Alloy Phases on the Performance of Bimetallic In-Pd Catalysts for CO2 Hydrogenation to Methanol.
- M., K. W. M. D. H. H. J. S. (2019). Robust and biocompatible catalysts for efficient hydrogen-driven microbial electrosynthesis.
- F., T. H. V. G. S. D. J. (2019). Development of Molybdenum Phosphide Catalysts for Higher Alcohol Synthesis from Syngas by Exploiting Support and Promoter Effects.
Methane Conversion to Liquid Fuels and Chemicals Annual Report
Stanford Natural Gas Initiative seed funded projects require annual submissions of brief technical progress reports and interim report summaries for active projects. Closed projects require a technical report and final report summary one year after the award close date.